Drill cutting samples (n = 92) from the Devonian Awaynat Wanin Formation and Silurian Tanezzuft Formation, sampled from three wells F1, G1 and H1, locate in the northern edge of the Murzuq basin (approximately 700 kilometers south of Tripoli). The studied samples were analyzed in the objective of their organic geochemical assessment such as the type of organic matter, depositional conditions and thermal maturity level. A bulk geochemical parameters and precise biomarkers were estimated, using chromatography-mass spectrometry (GC-MS) to reveal a diversity of their geochemical characterizations. The rock formations are having varied organic matter contents, ranged from fair to excellent. The total organic carbon (TOC) reached about 9.1 wt%, ranging from 0.6 to 2.93 wt% (Awaynat Wanin), 0.5 to 2.54 wt% (Tanezzuft) and 0.52 to 9.1 wt% (Hot Shale). The cutting samples are ranged oil-prone organic matter (OM) of hydrogen index (HI) ranged between 98 –396 mg HC/g TOC, related kerogen types are type II and II/III, with oxygen index (OI): 6 - 190 with one sample have value of 366 mg CO2/g. Thermal maturity of these source rocks is different, ranging from immature to mature and oil window in the most of Tanezzuft Formation and Hot Shale samples, as reflected from the production index data (PI: 0.08 - 034). Tmax and vitrinite reflectance Ro% data (Tmax: 435 – 454 & Ro%: 0.46 - 1.38) for the Awaynat Wanin. Biomarker ratios of specific hydrocarbons extracted from represented samples (n = 9), were moreover used to study thermal maturity level and depositional environments. Pristine/Phytane (Pr/Ph) ratios of 1.65 - 2.23 indicated anoxic to suboxic conditions of depositional marine shale and lacustrine source rock.

The paper presents new studies on numerical modeling (FEM) for beam-to-column behavior under sagging and hogging bending moment when the framework is exposed to service and unexpected loads that may cause a column loss scenario. This investigation is focused on four bolts end-plate joints with 10 mm thickness which are proven experimentally to have more ductile behavior than other end-plates joints (6, 8 bolts), spite of their weakness to transfer the unexpected loads from the initial state to a residual state of the stable equilibrium, that leads to a failure of limited floor area to adjacent joints when tested experimentally (Saleh, 2014). FEM technique used in this research is an extension of the previous technique and is characterized by the use of a more sophisticated technique than the previous, discovered from the result of continuous research and the use of all the options available in the new version of commercial ABAQUS/CAD software. The elements are designed using multiple layers of specific elements of a brick arranged in such a way that the mesh nodes of the tiles should coincide with certain layers with the top of the shear inlay and in line with reinforcement, not as the former study that used thick shell elements to model the reinforced concrete slab with total negligence of reinforcing steel and bolts between the slap and the beam. This investigation is very complex because of highly nonlinear effects associated with the prediction of joint performance, such as structural imperfections, huge displacements and large rotations, inelastic properties of steel and concrete, bonding effects between steel and concrete, friction between …

This search aims to apply developed geochemical methods to a number of oils and source rock extracts to better establish the features of ancient environments that occurred in the Murzuq basin. Geochemical and geophysical approaches were used to confirm further a source contribution from other Paleozoic formations to hydrocarbon accumulations in the basin. One hundred and forty rock units were collected from B1-NC151, D1-NC174, A1-NC 76, D1-NC 151, F1-NC58, A1-NC 186, P1-NC 101, D1-NC 58, H1-NC58 and A1-NC58 wells. Seven crude oils were collocated A1-NC186, B1-NC186, E2-NC101, F3-NC174, A10-NC115, B10-NC115 and H10-NC115 wells. A geochemical assessment of the studied rocks and oils was done by means of geochemical parameters of total organic carbon (TOC), Rock-Eval analysis, detailed-various biomarkers and stable carbon isotope. The TOC values from B1-NC151 range 0.40% to 8.5%, A1-NC186 0.3% and 1.45, A1-NC76 0.39% to 0.74%, D1-NC151 0.40% to 2.00% to F1-NC58 0.40% to 1.12%. D1_NC174 0.30% to 10 %, P1-NC101 0.80% to 1.35%, D1-NC58 0.5% to 1.10%, H1-NC58 0.20% to 3.50%, A1-NC58 0.40% to 1.60%. The categories of organic matter from rock-eval pyrolysis statistics point to that type II kerogen is the main type, in association with type III, and no of type I kerogen recognized. Vitrinite reflectance (%Ro), Tmax and Spore colour index (SCI) as thermal maturity parameters reflect that the measured rock units are have different maturation levels, ranging from immature to mature sources. acritarchs distribution for most samples could be recognized and Palynomorphs are uncommon. Pristane to phytane ratios (> 1) revealed marine shale to lacustrine of environmental deposition. The Stable carbon isotope (δ 13C) values of seven rock-extract samples are -30.98‰ and -29.14‰ of saturates and -29.86‰ to -28.37‰ aromatic fractions. The oil saturate hydrocarbon fractions range between -29.36‰ to -28.67‰ and aromatic are among -29.98 ‰ to -29.55 ‰. The δ 13C data in both rock extractions and crude oils are closer to each other, typical in sign of Paleozoic age. It is clear that the base of Tanezzuft Formation (Hot shale) is considered the main source rocks. The Devonian Awaynat Wanin Formation as well locally holds sufficient oil prone kerogen to consider as potential source rocks. Ordovician Mamuniyat Formation shales may poorly contain oil prone kerogen to be addressed in future studies. An assessment of the correlations between the oils and potential source rocks and between the oils themselves indicated that most of the rocks extracts were broadly similar to most of the oils and supported by carbon stable isotope analysis results. 

The aim of the present paper is focused on nucleation onset and development morphologies of acicular ferrite and to evaluate microstructure and mechanical properties during isothermal austenite transformation in titanium free micro-alloyed steel. Isothermal treatment was carried out in the temperature range 350 to 450 C. These treatments were interrupted at different times between 2 and 1800 s in order to analyze the evolution of the microstructure. Yield stress was determined by compression testing on samples with final Microstructure. The metallographic evaluation was done by using optical and scanning electron microscopy (SEM) enabled determination of the nucleation onset at all treatments and subsequent on the development of acicular ferrite of isothermally treated titanium free micro-alloyed steel. The results show that during continuous cooling, dominantly acicular ferrite microstructure is formed. Main characteristics of acicular ferrite are intragranular nucleation and strongly disorganized microstructure with a larger ability to deflect cracks. Acicular ferrite is, therefore, widely recognized to be a desirable microstructure due to good mechanical properties.