Using natural gas as a fuel for internal combustion engine (spark ignition) results in reduction of pollutant emission such as NOx, HC, CO and SOOT if compared with conventional hydrocarbon fuel in addition the high-octane number of natural gas allows an increase of compression ratio in spark ignition engine and consequently improves their efficiency.

In this paper an extension of the model presented by Ferguson [1], is applied using FORTRAN language. A comprehensive performance data is presented for equivalence ratios, compression ratios, and engine speed. The contributions were to develop and validate a computer code simulation for 4-stroke cycle SI engine by using different fuel and compare the results with previous experimental studies. The results of the computer code are in very good agreement with the experimental studies under various conditions.

Experiments showed that a compression ratio of 12:1 is a reasonable value for a compressed-natural-gas direct-injection engine to obtain a better thermal efficiency without a large penalty of emissions.

لقد تزايد الاهتمام المحلي والدولي بمكافحة الفساد المالي والإداري وخاصة في ظل التطورات المتلاحقة للحياة الإقتصادية والتي تُحتم على منظمات الأعمال ضرورة مكافحة الفساد المالي والإداري حتى يتسنى لها البقاء الأمن في بيئة الأعمال. وتعد المحاسبة القضائية من الآليات الحديثة في مجال منع واكتشاف الغش والفساد المالي والإداري، لذا فقد هدفت هذه الدراسة إلى التعرف المفاهيم الأساسية للمحاسبة القضائية و توضيح السمات الشخصية التي يجب أن يتميز بها و التعرف على المعايير المهنية الصادرة عن جمعية ممتحني الاحتيال المعتمدين بخصوص ممارسة مهنة المحاسبة القضائية، ولتحقيق هذه الاهداف تم تقسيم الدراسة إلى ثلاثة اجزاء، تناول الجزء الاول الاطار العام للدراسة وتناول الجزء الثاني الإطار النظري للمحاسبة القضائية في حين خصص الجزء الثالث للدراسة الميدانية والذي تم فيه اختبار مدى توفر تلك المعايير الدولية في ممارسي مهنة المحاسب القضائي في ليبيا، وقد خلصت الدراسة إلى عدم توفر تلك المعايير مما يستوجب ضرورة العمل على تطوير القدرات والمهارات لدى المحاسب القضائي حتى يتسنى له أداء مهامه بكل كفاءة واقتدار.

Abstract

It has been described the development of electrochemical nano sensor for the detection of mercury ions from aqueous solutions based on the formation of polyaniline nanoparticle films. Screen printed carbon electrodes were modified with polyaniline nanoparticles. Electropolymerization of polyaniline nanoparticles was performed by the pulsed potentiostatic method. The sample of polyaniline nanoparticles was prepared by repeating the potential step process three times. Structural and morploigcal characterization of polyaniline nanoparticles modified screen printed carbon electrode was performed using Fourier Transmission infrared (FTIR), X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). PANI nanoparticles were spherical shaped having an apparent dimeter varying from 20 to 45 nm. Square wave anodic stripping voltammetry was used for the detection of Hg(II) on PANI NPs modified screen printed carbon electrode under optimized conditions. Hg(II) was deposited for 60 seconds by the reduction of Hg(II) in buffer solution:(citric acid and sodium chloride pH 2.30), followed by Hg stripping between 0.3 and 0.8 V at the following parameters: Scan rate: 100 mV s-1, frequency: 60 Hz, amplitude: 0.025 V and increment: 4.0 mV. it was found that the PANI NPs modified screen printed carbon electrode had a highest anodic stripping peak current in solution of pH 2.30. The limit of detection value for Hg(II) was found to be 2.50 ± 0.03 ppb. The limits of detections determined are below the corresponding guideline value from the World Health Organization (WHO). In addition, the modified nano electrode exhibited excellent reproducibility and high stability. The developed method was successfully applied to determine Hg(II) in real water samples with satisfactory results.

Data required for calculation the static re-crystallization kinetics have been evaluated from laboratory simulations. Series of two hit isothermal tests were conducted on high temperature torsion machine. These tests were conducted on four different temperatures and using inter-pass times between 0.5 and 5s with aim to investigate the influence of thermal activation on static re-crystallization. All tests were conducted on temperatures over TNR temperature, i.e. in temperature range in which all niobium is present only in solid solution. Method of evaluation of re-crystallization fraction was mechanical metallography, i.e. evaluation based on shape of each stress- strain curve. The fraction softening was calculated for all temperatures, together with avrami exponent, nA, and activation energy for re-crystallization, QSRX. Activation energy for static re-crystallization QSRX  281 KJ/mol and avrami exponent nA  1 determined in this work are in excellent agreement with previously reported data.

The aim of this work is focused on nucleation stages with emphasis on the development of intra-granular ferrite morphologies during isothermal austenite transformation in titanium free micro-alloyed steel. Isothermal treatment was carried out in the temperature range 350 to 600οC. These treatments were interrupted at different times between 2 and 1800 s in order to analyze the evolution of the microstructure. Metallographic evaluation was done by using optical and scanning electron microscopy (SEM) enabled determination of the nucleation onset at all treatments and subsequent on the development of intra-granular ferrite of isothermally treated Ti free micro-alloyed steel. The results show that at high temperatures ( 500  C) polygonal intra-granularly nucleated ferrite idiomorphs, combined with grain boundary ferrite and pearlite were produced and followed by an incomplete transformation phenomenon, At intermediate temperatures (450 and 500  C) an interlocked acicular ferrite (AF) microstructure is produced, and at low temperatures (400 and 350  C) the sheave of parallel acicular ferrite plates, similar to bainitic sheaves but intra-granularly nucleated were observed. In addition to sheaf type acicular ferrite, the grain boundary nucleated bainitic sheaves are observed.