The oil and gas sector has a significant impact on sustainable development, making it important for the sector to implement serious changes in the way it does business. Oil and gas operations involve both upstream activities, and downstream activities. Due to the nature of these activities which cause high risks, companies work continuously to reduce the significance of their adverse impacts on the environment and people. Thus, evaluating the sustainable production in this sector is become a necessity. This paper proposes a set of Key Performance Indicators (KPIs) for evaluating the sustainable production believed to be appropriate to the oil and gas sector based on the triple bottom line of sustainability. The Analytical Hierarchy Process (AHP) method is applied to prioritize the performance indicators by summarizing the opinions of experts. It is hoped that the proposed KPIs enables and assists this sector to achieve the higher performance in sustainable production and so as to ensures business sustainability.

Abstract

Swirl stabilized combustion is one of the most successful technologies for flame and nitrogen oxides control in gas turbines. However, complex fluid dynamics and lean conditions pose a problem for stabilization of the flame. The problem is even more acute when alternative fuels are used for flexible operation. Although there is active research on the topic, there are still various gaps in the understanding of how interaction of large coherent structures during the process affect flame stabilization and related phenomena. Thus, this paper approaches the phenomenon of lean premixed swirl combustion of CH4/H2/CO blends to understand the impacts of these fuels on flame blowoff. An atmospheric pressure generic swirl burner was operated at ambient inlet conditions. Different exhaust nozzles were used to alter the Central Recirculation Zone and observe the impacts caused by various fuel blends on the structure and the blowoff phenomenon. Methane content in the fuel was decreased from 50% to 10% (by volume) with the remaining amount split equally between carbon monoxide and hydrogen. Experimental trials were performed using Phase Locked PIV. The Central Recirculation Zone and its velocity profiles were measured and correlated providing details of the structure close to blowoff. The results show how the strength and size of the recirculation zone are highly influenced by the fuel blend, changing stability based on the carbon-hydrogen ratios. Nozzle effects on the shear flow and Re numbers were also observed. Modelling was carried out using the k-ω SST CFD model which provided more information about the impact of the CRZ and the flame nature close to blowoff limit. It was observed that the model under-predicts coherent structure interactions at high methane fuel content, with an over-prediction of pressure decay at low methane content when correlated to the experimental results. Thus, complex interactions between structures need to be included for adequate power prediction when using very fast/slow syngas blends under lean conditions. 

لقد تزايد الاهتمام المحلي والدولي بمكافحة الفساد المالي والإداري وخاصة في ظل التطورات المتلاحقة للحياة الإقتصادية والتي تُحتم على منظمات الأعمال ضرورة مكافحة الفساد المالي والإداري حتى يتسنى لها البقاء الأمن في بيئة الأعمال. وتعد المحاسبة القضائية من الآليات الحديثة في مجال منع واكتشاف الغش والفساد المالي والإداري، لذا فقد هدفت هذه الدراسة إلى التعرف المفاهيم الأساسية للمحاسبة القضائية و توضيح السمات الشخصية التي يجب أن يتميز بها و التعرف على المعايير المهنية الصادرة عن جمعية ممتحني الاحتيال المعتمدين بخصوص ممارسة مهنة المحاسبة القضائية، ولتحقيق هذه الاهداف تم تقسيم الدراسة إلى ثلاثة اجزاء، تناول الجزء الاول الاطار العام للدراسة وتناول الجزء الثاني الإطار النظري للمحاسبة القضائية في حين خصص الجزء الثالث للدراسة الميدانية والذي تم فيه اختبار مدى توفر تلك المعايير الدولية في ممارسي مهنة المحاسب القضائي في ليبيا، وقد خلصت الدراسة إلى عدم توفر تلك المعايير مما يستوجب ضرورة العمل على تطوير القدرات والمهارات لدى المحاسب القضائي حتى يتسنى له أداء مهامه بكل كفاءة واقتدار.

Abstract

It has been described the development of electrochemical nano sensor for the detection of mercury ions from aqueous solutions based on the formation of polyaniline nanoparticle films. Screen printed carbon electrodes were modified with polyaniline nanoparticles. Electropolymerization of polyaniline nanoparticles was performed by the pulsed potentiostatic method. The sample of polyaniline nanoparticles was prepared by repeating the potential step process three times. Structural and morploigcal characterization of polyaniline nanoparticles modified screen printed carbon electrode was performed using Fourier Transmission infrared (FTIR), X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). PANI nanoparticles were spherical shaped having an apparent dimeter varying from 20 to 45 nm. Square wave anodic stripping voltammetry was used for the detection of Hg(II) on PANI NPs modified screen printed carbon electrode under optimized conditions. Hg(II) was deposited for 60 seconds by the reduction of Hg(II) in buffer solution:(citric acid and sodium chloride pH 2.30), followed by Hg stripping between 0.3 and 0.8 V at the following parameters: Scan rate: 100 mV s-1, frequency: 60 Hz, amplitude: 0.025 V and increment: 4.0 mV. it was found that the PANI NPs modified screen printed carbon electrode had a highest anodic stripping peak current in solution of pH 2.30. The limit of detection value for Hg(II) was found to be 2.50 ± 0.03 ppb. The limits of detections determined are below the corresponding guideline value from the World Health Organization (WHO). In addition, the modified nano electrode exhibited excellent reproducibility and high stability. The developed method was successfully applied to determine Hg(II) in real water samples with satisfactory results.

Data required for calculation the static re-crystallization kinetics have been evaluated from laboratory simulations. Series of two hit isothermal tests were conducted on high temperature torsion machine. These tests were conducted on four different temperatures and using inter-pass times between 0.5 and 5s with aim to investigate the influence of thermal activation on static re-crystallization. All tests were conducted on temperatures over TNR temperature, i.e. in temperature range in which all niobium is present only in solid solution. Method of evaluation of re-crystallization fraction was mechanical metallography, i.e. evaluation based on shape of each stress- strain curve. The fraction softening was calculated for all temperatures, together with avrami exponent, nA, and activation energy for re-crystallization, QSRX. Activation energy for static re-crystallization QSRX  281 KJ/mol and avrami exponent nA  1 determined in this work are in excellent agreement with previously reported data.

The aim of this work is focused on nucleation stages with emphasis on the development of intra-granular ferrite morphologies during isothermal austenite transformation in titanium free micro-alloyed steel. Isothermal treatment was carried out in the temperature range 350 to 600οC. These treatments were interrupted at different times between 2 and 1800 s in order to analyze the evolution of the microstructure. Metallographic evaluation was done by using optical and scanning electron microscopy (SEM) enabled determination of the nucleation onset at all treatments and subsequent on the development of intra-granular ferrite of isothermally treated Ti free micro-alloyed steel. The results show that at high temperatures ( 500  C) polygonal intra-granularly nucleated ferrite idiomorphs, combined with grain boundary ferrite and pearlite were produced and followed by an incomplete transformation phenomenon, At intermediate temperatures (450 and 500  C) an interlocked acicular ferrite (AF) microstructure is produced, and at low temperatures (400 and 350  C) the sheave of parallel acicular ferrite plates, similar to bainitic sheaves but intra-granularly nucleated were observed. In addition to sheaf type acicular ferrite, the grain boundary nucleated bainitic sheaves are observed.